methyl (E,5R,7R)-8-[(2S,3R,4R,4aS,6R,7R,8aS)-7-[tert-butyl(diphenyl)silyl]oxy-6-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-3-[(4-methoxyphenyl)methoxy]-4-methyl-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran-2-yl]-2-[[(2S,5S)-5-[3-(2,2-dimethylpropanoyloxy)propyl]-3-methylidene-oxolan-2-yl]methyl]-5-methyl-6-methylidene-7-oxidanyl-oct-2-enoate

Systemtic Name: methyl (E,5R,7R)-8-[(2S,3R,4R,4aS,6R,7R,8aS)-7-[tert-butyl(diphenyl)silyl]oxy-6-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-3-[(4-methoxyphenyl)methoxy]-4-methyl-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran-2-yl]-2-[[(2S,5S)-5-[3-(2,2-dimethylpropanoyloxy)propyl]-3-methylidene-oxolan-2-yl]methyl]-5-methyl-6-methylidene-7-oxidanyl-oct-2-enoate Openeye Name: methyl (E,5R,7R)-8-[(2S,3R,4R,4aS,6R,7R,8aS)-7-[tert-butyl(diphenyl)silyl]oxy-6-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-3-[(4-methoxyphenyl)methoxy]-4-methyl-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran-2-yl]-2-[[(2S,5S)-5-[3-(2,2-dimethylpropanoyloxy)propyl]-3-methylene-tetrahydrofuran-2-yl]methyl]-7-hydroxy-5-methyl-6-methylene-oct-2-enoate CAS Name: (E,5R,7R)-8-[(2S,3R,4R,4aS,6R,7R,8aS)-7-[tert-butyl(diphenyl)silyl]oxy-6-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-3-[(4-methoxyphenyl)methoxy]-4-methyl-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran-2-yl]-2-[[(2S,5S)-5-[3-(2,2-dimethyl-1-oxopropoxy)propyl]-3-methylene-2-oxolanyl]methyl]-7-hydroxy-5-methyl-6-methylene-2-octenoic acid methyl ester IUPAC Name: methyl (E,5R,7R)-8-[(2S,3R,4R,4aS,6R,7R,8aS)-7-[tert-butyl(diphenyl)silyl]oxy-6-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-3-[(4-methoxyphenyl)methoxy]-4-methyl-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran-2-yl]-2-[[(2S,5S)-5-[3-(2,2-dimethylpropanoyloxy)propyl]-3-methylideneoxolan-2-yl]methyl]-7-hydroxy-5-methyl-6-methylideneoct-2-enoate Traditional Name: (2E,5R)-6-[(1R)-2-[(2S,3R,4R,4aS,6R,7R,8aS)-7-[tert-butyl(diphenyl)silyl]oxy-6-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-4-methyl-3-p-anisyloxy-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran-2-yl]-1-hydroxy-ethyl]-5-methyl-2-[[(2S,5S)-3-methylene-5-(3-pivaloyloxypropyl)tetrahydrofuran-2-yl]methyl]hepta-2,6-dienoic acid methyl ester Formula: C76H102O12Si2 MolecularWeight: 1263.78688

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Descriptors Computed from Structure

Canonical SMILES:

CC1C2C(CC(C(O2)CCO[Si](C3=CC=CC=C3)(C4=CC=CC=C4)C(C)(C)C)O[Si](C5=CC=CC=C5)(C6=CC=CC=C6)C(C)(C)C)OC(C1OCC7=CC=C(C=C7)OC)CC(C(=C)C(C)CC=C(CC8C(=C)CC(O8)CCCOC(=O)C(C)(C)C)C(=O)OC)O

Isomeric SMILES

C[C@H]1[C@H]2[C@H](C[C@H]([C@H](O2)CCO[Si](C3=CC=CC=C3)(C4=CC=CC=C4)C(C)(C)C)O[Si](C5=CC=CC=C5)(C6=CC=CC=C6)C(C)(C)C)O[C@H]([C@@H]1OCC7=CC=C(C=C7)OC)C[C@H](C(=C)[C@H](C)C/C=C(\C[C@H]8C(=C)C[C@@H](O8)CCCOC(=O)C(C)(C)C)/C(=O)OC)O

InChI

InChI=1S/C76H102O12Si2/c1-52(38-41-57(72(78)81-15)48-66-53(2)47-59(85-66)29-28-45-82-73(79)74(5,6)7)54(3)64(77)49-68-70(83-51-56-39-42-58(80-14)43-40-56)55(4)71-69(86-68)50-67(88-90(76(11,12)13,62-34-24-18-25-35-62)63-36-26-19-27-37-63)65(87-71)44-46-84-89(75(8,9)10,60-30-20-16-21-31-60)61-32-22-17-23-33-61/h16-27,30-37,39-43,52,55,59,64-71,77H,2-3,28-29,38,44-51H2,1,4-15H3/b57-41+/t52-,55-,59+,64-,65-,66+,67-,68+,69+,70-,71+/m1/s1