(3R,4S,5S,6R,7R,9R,10E,11S,12R,13S,14R)-10-[(2-chlorophenyl)methoxyimino]-6-[(2S,3R,4S,6R)-4-(dimethylamino)-6-methyl-3-trimethylsilyloxy-oxan-2-yl]oxy-14-ethyl-7-methoxy-4-[(2R,4R,5S,6S)-4-methoxy-4,6-dimethyl-5-trimethylsilyloxy-oxan-2-yl]oxy-3,5,7,9,11,13-hexamethyl-12,13-bis(oxidanyl)-1-oxacyclotetradecan-2-one

Systemtic Name: (3R,4S,5S,6R,7R,9R,10E,11S,12R,13S,14R)-10-[(2-chlorophenyl)methoxyimino]-6-[(2S,3R,4S,6R)-4-(dimethylamino)-6-methyl-3-trimethylsilyloxy-oxan-2-yl]oxy-14-ethyl-7-methoxy-4-[(2R,4R,5S,6S)-4-methoxy-4,6-dimethyl-5-trimethylsilyloxy-oxan-2-yl]oxy-3,5,7,9,11,13-hexamethyl-12,13-bis(oxidanyl)-1-oxacyclotetradecan-2-one Openeye Name: (3R,4S,5S,6R,7R,9R,10E,11S,12R,13S,14R)-10-[(2-chlorophenyl)methoxyimino]-6-[(2S,3R,4S,6R)-4-(dimethylamino)-6-methyl-3-trimethylsilyloxy-tetrahydropyran-2-yl]oxy-14-ethyl-12,13-dihydroxy-7-methoxy-4-[(2R,4R,5S,6S)-4-methoxy-4,6-dimethyl-5-trimethylsilyloxy-tetrahydropyran-2-yl]oxy-3,5,7,9,11,13-hexamethyl-oxacyclotetradecan-2-one CAS Name: (3R,4S,5S,6R,7R,9R,10E,11S,12R,13S,14R)-10-[(2-chlorophenyl)methoxyimino]-6-[[(2S,3R,4S,6R)-4-(dimethylamino)-6-methyl-3-trimethylsilyloxy-2-oxanyl]oxy]-14-ethyl-12,13-dihydroxy-7-methoxy-4-[[(2R,4R,5S,6S)-4-methoxy-4,6-dimethyl-5-trimethylsilyloxy-2-oxanyl]oxy]-3,5,7,9,11,13-hexamethyl-oxacyclotetradecan-2-one IUPAC Name: (3R,4S,5S,6R,7R,9R,10E,11S,12R,13S,14R)-10-[(2-chlorophenyl)methoxyimino]-6-[(2S,3R,4S,6R)-4-(dimethylamino)-6-methyl-3-trimethylsilyloxyoxan-2-yl]oxy-14-ethyl-12,13-dihydroxy-7-methoxy-4-[(2R,4R,5S,6S)-4-methoxy-4,6-dimethyl-5-trimethylsilyloxyoxan-2-yl]oxy-3,5,7,9,11,13-hexamethyl-oxacyclotetradecan-2-one Traditional Name: (3R,4S,5S,6R,7R,9R,10E,11S,12R,13S,14R)-10-(2-chlorobenzyl)oximino-6-[(2S,3R,4S,6R)-4-(dimethylamino)-6-methyl-3-trimethylsilyloxy-tetrahydropyran-2-yl]oxy-14-ethyl-12,13-dihydroxy-7-methoxy-4-[(2R,4R,5S,6S)-4-methoxy-4,6-dimethyl-5-trimethylsilyloxy-tetrahydropyran-2-yl]oxy-3,5,7,9,11,13-hexamethyl-oxacyclotetradecan-2-one Formula: C51H91ClN2O13Si2 MolecularWeight: 1031.89784

Click to see the large picture

Descriptors Computed from Structure

Canonical SMILES:

CCC1C(C(C(C(=NOCC2=CC=CC=C2Cl)C(CC(C(C(C(C(C(=O)O1)C)OC3CC(C(C(O3)C)O[Si](C)(C)C)(C)OC)C)OC4C(C(CC(O4)C)N(C)C)O[Si](C)(C)C)(C)OC)C)C)O)(C)O

Isomeric SMILES

CC[C@@H]1[C@@]([C@@H]([C@H](/C(=N/OCC2=CC=CC=C2Cl)/[C@@H](C[C@@]([C@@H]([C@H]([C@@H]([C@H](C(=O)O1)C)O[C@H]3C[C@@]([C@H]([C@@H](O3)C)O[Si](C)(C)C)(C)OC)C)O[C@H]4[C@@H]([C@H](C[C@H](O4)C)N(C)C)O[Si](C)(C)C)(C)OC)C)C)O)(C)O

InChI

InChI=1S/C51H91ClN2O13Si2/c1-21-39-51(10,57)44(55)32(4)41(53-60-29-36-24-22-23-25-37(36)52)30(2)27-49(8,58-13)45(65-48-43(66-68(15,16)17)38(54(11)12)26-31(3)61-48)33(5)42(34(6)47(56)63-39)64-40-28-50(9,59-14)46(35(7)62-40)67-69(18,19)20/h22-25,30-35,38-40,42-46,48,55,57H,21,26-29H2,1-20H3/b53-41+/t30-,31-,32+,33+,34-,35+,38+,39-,40+,42+,43-,44-,45-,46+,48+,49-,50-,51-/m1/s1