[(1S,6S)-6-[tert-butyl(dimethyl)silyl]oxy-3-(trifluoromethylsulfonyloxy)cyclohex-2-en-1-yl] (1R,4S)-1,7,7-trimethyl-2-oxidanylidene-3-oxabicyclo[2.2.1]heptane-4-carboxylate

Systemtic Name: [(1S,6S)-6-[tert-butyl(dimethyl)silyl]oxy-3-(trifluoromethylsulfonyloxy)cyclohex-2-en-1-yl] (1R,4S)-1,7,7-trimethyl-2-oxidanylidene-3-oxabicyclo[2.2.1]heptane-4-carboxylate Openeye Name: [(1S,6S)-6-[tert-butyl(dimethyl)silyl]oxy-3-(trifluoromethylsulfonyloxy)cyclohex-2-en-1-yl] (1R,4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carboxylate CAS Name: (1R,4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carboxylic acid [(1S,6S)-6-[tert-butyl(dimethyl)silyl]oxy-3-(trifluoromethylsulfonyloxy)-1-cyclohex-2-enyl] ester IUPAC Name: [(1S,6S)-6-[tert-butyl(dimethyl)silyl]oxy-3-(trifluoromethylsulfonyloxy)cyclohex-2-en-1-yl] (1R,4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carboxylate Traditional Name: (1R,4S)-2-keto-1,7,7-trimethyl-3-oxabicyclo[2.2.1]heptane-4-carboxylic acid [(1S,6S)-6-[tert-butyl(dimethyl)silyl]oxy-3-triflyloxy-cyclohex-2-en-1-yl] ester Formula: C23H35F3O8SSi MolecularWeight: 556.66491

Click to see the large picture

Descriptors Computed from Structure

Canonical SMILES:

CC1(C2(CCC1(OC2=O)C(=O)OC3C=C(CCC3O[Si](C)(C)C(C)(C)C)OS(=O)(=O)C(F)(F)F)C)C

Isomeric SMILES

C[C@@]12CC[C@@](C1(C)C)(OC2=O)C(=O)O[C@H]3C=C(CC[C@@H]3O[Si](C)(C)C(C)(C)C)OS(=O)(=O)C(F)(F)F

InChI

InChI=1S/C23H35F3O8SSi/c1-19(2,3)36(7,8)34-15-10-9-14(33-35(29,30)23(24,25)26)13-16(15)31-18(28)22-12-11-21(6,17(27)32-22)20(22,4)5/h13,15-16H,9-12H2,1-8H3/t15-,16-,21-,22+/m0/s1